ExamSpark Class 12 Chemistry

Mock Test 10 Performance Solutions

Subject: CBSE Class 12 Chemistry (NCERT Full-Syllabus Practice)

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Detailed Question Analysis

Q1. The correct expression for rate of reaction is:

Correct Answer: Option B (\(-d[\mathrm{reactant}]/dt\))

Concept Explanation: Rate of reaction is defined as decrease in concentration of reactant per unit time.

Q2. Which electrolyte shows maximum van't Hoff factor?

Correct Answer: Option D (Al 2 (SO 4 ) 3)

Concept Explanation: Al 2 (SO 4 ) 3 dissociates into 5 ions, giving highest particle number.

Q3. In crystal field theory, octahedral splitting results in:

Correct Answer: Option B (\(t_{2g}\) lower, \(e_g\) higher)

Concept Explanation: d-orbitals split into lower \(t_{2g}\) and higher \(e_g\) levels.

Q4. Strongest reducing agent among halides:

Correct Answer: Option D (I ^-)

Concept Explanation: I ^- is most easily oxidized due to large size.

Q5. Which polymer is biodegradable?

Correct Answer: Option B (PHBV)

Concept Explanation: PHBV is a biodegradable polyester used in medical applications.

Q6. A first-order reaction has rate constant k. Unit of k is:

Correct Answer: Option C (s ^- 1)

Concept Explanation: First-order rate constant has unit time ^- 1.

Q7. Conductivity increases with dilution because:

Correct Answer: Option B (ions move freely)

Concept Explanation: Reduced interionic attraction increases ion mobility.

Q8. Which complex shows optical isomerism?

Correct Answer: Option B ([Cr(en)3]3+)

Concept Explanation: Chelating ligands create chiral complexes.

Q9. Hydrogen bonding strongest in:

Correct Answer: Option A (HF)

Concept Explanation: Fluorine has highest electronegativity.

Q10. Oxidation state of Mn in KMnO 4 :

Correct Answer: Option C (+7)

Concept Explanation: K(+1) + Mn + 4(-2) = 0 \(\rightarrow\) Mn = +7.

Q11. Rusting is prevented by:

Correct Answer: Option B (galvanization)

Concept Explanation: Zinc coating prevents iron oxidation.

Q12. Antihistamine drug:

Correct Answer: Option B (Chlorpheniramine)

Concept Explanation: Blocks histamine receptors in allergic reactions.

Q13. Biomagnification is maximum in:

Correct Answer: Option D (top carnivores)

Concept Explanation: Toxic concentration increases at higher trophic levels.

Q14. Assertion (A): Molecularity is always positive integer. Reason (R): It is based on elementary reaction step.

Correct Answer: Option A (Both true and R explains A)

Concept Explanation: Molecularity refers to actual reacting molecules.

Q15. Assertion (A): Catalyst changes equilibrium constant. Reason (R): Catalyst lowers activation energy equally for forward and reverse reactions.

Correct Answer: Option B (A false R true)

Concept Explanation: Catalyst does not change equilibrium constant.

Q16. Case Study: A student observes faster reaction at higher temperature. Reason:

Correct Answer: Option B (more effective collisions)

Concept Explanation: Higher temperature increases kinetic energy.

Q17. Case Study: Electrolyte increases boiling point elevation. Reason:

Correct Answer: Option B (more particles)

Concept Explanation: More ions increase colligative effect.

Q18. Highest conductivity:

Correct Answer: Option C (HCl)

Concept Explanation: HCl is strong electrolyte.

Q19. Half-life of first-order reaction depends on:

Correct Answer: Option B (temperature)

Concept Explanation: Depends only on rate constant.

Q20. Strongest intermolecular force:

Correct Answer: Option B (\(\mathrm{NH_3}\))

Concept Explanation: \(\mathrm{NH_3}\) exhibits hydrogen bonding.

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