ExamSpark Class 12 Chemistry

Mock Test 09 Performance Solutions

Subject: CBSE Class 12 Chemistry (NCERT Full-Syllabus Practice)

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Detailed Question Analysis

Q1. The unit of rate constant for a third-order reaction is:

Correct Answer: Option C (L2 mol ^- 2 s ^- 1)

Concept Explanation: For third-order reactions, unit of rate constant is L2 mol ^- 2 s ^- 1.

Q2. Which solution exhibits the greatest colligative effect?

Correct Answer: Option C (0.1 M CaCl 2)

Concept Explanation: CaCl 2 dissociates into 3 ions, giving highest van't Hoff factor.

Q3. In crystal field theory, tetrahedral complexes are:

Correct Answer: Option A (always high spin)

Concept Explanation: \(\Delta\) t is small, so pairing energy is not overcome \(\rightarrow\) high spin.

Q4. The strongest oxidizing agent among the following is:

Correct Answer: Option D (F 2)

Concept Explanation: Fluorine has highest electronegativity and strongest oxidizing power.

Q5. Which polymer is used for making bulletproof jackets?

Correct Answer: Option C (Kevlar)

Concept Explanation: Kevlar has strong intermolecular hydrogen bonding and high tensile strength.

Q6. A reaction shows rate proportional to square of concentration. Order is:

Correct Answer: Option C (2)

Concept Explanation: Order equals sum of powers in rate law.

Q7. Conductivity increases with dilution because:

Correct Answer: Option B (ions move freely)

Concept Explanation: Reduced interionic attraction increases mobility.

Q8. Which complex shows geometrical isomerism?

Correct Answer: Option B ([Pt(\(\mathrm{NH_3}\))2Cl2])

Concept Explanation: Square planar complexes show cis-trans isomerism.

Q9. Hydrogen bonding is strongest in:

Correct Answer: Option A (HF)

Concept Explanation: F is most electronegative, strongest H-bonding.

Q10. Oxidation state of Cr in \(\mathrm{K_2Cr_2O_7}\) is:

Correct Answer: Option C (+6)

Concept Explanation: 2Cr + 2(+1) + 7(-2) = 0 \(\rightarrow\) Cr = +6.

Q11. Rusting of iron is faster in:

Correct Answer: Option C (salt water)

Concept Explanation: Electrolytes accelerate corrosion.

Q12. Which drug is used as antacid?

Correct Answer: Option B (Ranitidine)

Concept Explanation: Ranitidine reduces gastric acid secretion.

Q13. Biomagnification increases:

Correct Answer: Option B (upward trophic levels)

Concept Explanation: Toxins accumulate at higher trophic levels.

Q14. Assertion (A): Molecularity is always a whole number. Reason (R): It is based on elementary reaction step.

Correct Answer: Option A (Both true and R explains A)

Concept Explanation: Molecularity refers to actual reacting molecules in a step.

Q15. Assertion (A): Catalyst changes equilibrium constant. Reason (R): Catalyst speeds up both forward and backward reactions equally.

Correct Answer: Option B (A false R true)

Concept Explanation: Catalyst does not change equilibrium constant.

Q16. Case Study: A student observes faster dissolution of sugar in hot water. Reason:

Correct Answer: Option B (increased kinetic energy)

Concept Explanation: Higher temperature increases molecular motion.

Q17. Case Study: Addition of electrolyte increases boiling point elevation. Reason:

Correct Answer: Option B (more particles)

Concept Explanation: More particles increase colligative effect.

Q18. Highest conductivity is shown by:

Correct Answer: Option C (HCl)

Concept Explanation: HCl is a strong electrolyte.

Q19. Half-life of first-order reaction depends on:

Correct Answer: Option B (temperature)

Concept Explanation: t1/2 depends only on rate constant.

Q20. Strongest intermolecular force exists in:

Correct Answer: Option B (\(\mathrm{NH_3}\))

Concept Explanation: \(\mathrm{NH_3}\) exhibits hydrogen bonding.

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