ExamSpark Class 12 Chemistry

Mock Test 07 Performance Solutions

Subject: CBSE Class 12 Chemistry (NCERT Full-Syllabus Practice)

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Detailed Question Analysis

Q1. The correct expression for rate of reaction in terms of disappearance of reactant A is:

Correct Answer: Option B (\(-d[A]/dt\))

Concept Explanation: Rate of reaction is defined as decrease in concentration of reactant per unit time.

Q2. Which electrolyte has the highest degree of dissociation?

Correct Answer: Option B (HCl)

Concept Explanation: HCl is a strong acid and fully ionizes in solution.

Q3. In octahedral complexes, CFSE is maximum for:

Correct Answer: Option B (low-spin d ⁶)

Concept Explanation: Low-spin d ⁶ has maximum pairing and stabilization.

Q4. Which compound shows strongest hydrogen bonding?

Correct Answer: Option B (\(\mathrm{H_2O}\))

Concept Explanation: O–H bond is highly polar, leading to strong hydrogen bonding.

Q5. Oxidation state of S in H2SO4 is:

Correct Answer: Option C (+6)

Concept Explanation: 2(+1) + S + 4(-2) = 0 \(\rightarrow\) S = +6.

Q6. A reaction has rate law: Rate = k[A]2. Order is:

Correct Answer: Option C (2)

Concept Explanation: Sum of powers of concentration gives order = 2.

Q7. Molar conductivity increases on dilution because:

Correct Answer: Option B (ions move freely)

Concept Explanation: Reduced interionic attraction increases mobility.

Q8. Which complex shows linkage isomerism?

Correct Answer: Option B ([Co(NO2)(\(\mathrm{NH_3}\))5]2+)

Concept Explanation: NO2- can bind through N or O atoms.

Q9. Strongest oxidizing agent among halogens:

Correct Answer: Option D (F2)

Concept Explanation: Fluorine has highest electronegativity.

Q10. Which polymer is biodegradable?

Correct Answer: Option C (PHBV)

Concept Explanation: PHBV is a biodegradable polyester.

Q11. Rusting of iron requires:

Correct Answer: Option C (oxygen + water)

Concept Explanation: Both oxygen and moisture are essential.

Q12. Which drug is an antacid?

Correct Answer: Option B (Ranitidine)

Concept Explanation: Ranitidine reduces gastric acid secretion.

Q13. Biomagnification increases along:

Correct Answer: Option B (food chain upward)

Concept Explanation: Toxic substances accumulate at higher trophic levels.

Q14. Assertion (A): Molecularity is always positive integer. Reason (R): It is determined from balanced chemical equation.

Correct Answer: Option C (A true R false)

Concept Explanation: Molecularity is from elementary step, not balanced equation.

Q15. Assertion (A): Catalyst changes equilibrium constant. Reason (R): Catalyst speeds up both forward and reverse reactions equally.

Correct Answer: Option B (A false R true)

Concept Explanation: Catalyst does not change equilibrium constant.

Q16. Case Study: A student observes faster reaction rate at higher temperature. Reason:

Correct Answer: Option B (more effective collisions)

Concept Explanation: Higher temperature increases kinetic energy and effective collisions.

Q17. Case Study: Addition of electrolyte increases colligative properties. Reason:

Correct Answer: Option B (increases particle number)

Concept Explanation: More particles lead to higher effect.

Q18. Highest conductivity is shown by:

Correct Answer: Option C (HCl)

Concept Explanation: HCl is a strong electrolyte.

Q19. Half-life of first-order reaction depends on:

Correct Answer: Option B (temperature)

Concept Explanation: t1/2 depends only on rate constant k.

Q20. Strongest intermolecular force is found in:

Correct Answer: Option B (\(\mathrm{NH_3}\))

Concept Explanation: \(\mathrm{NH_3}\) shows hydrogen bonding.

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